Reich Collection
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Hans Reich's Collection
Carbonyl Chemistry
Principal C-C Bond-Forming Reactions Involving Carbonyl Compounds
Regiochemistry of Enolate Formation
Acidity of Bases and Substrates
Methods for the Preparation of Enolates
Nucleophilicity - Basicity Relationships
Lone Pair Nucleophilicity Trends
Overview of Enolate Alkylations
Nucleophilicity of Enolate Equivalents
Metalloenamines
Carbonium Ion Alkylation of Enol Silyl Ethers
Conjugate Addition - the Michael and Related Reactions
Conjugate Addition-Alkylation
The Aldol Reaction and Condensation
The Morita-Bayliss-Hillman Reaction - nucleophilic addition-aldol-elimination
The Acylation of Enolates - the Claisen and Dieckmann Condensations
The Acylation of Organometallic Reagents
The Mannich Condensation
α-X Carbon Nucleophiles - Methylenation and Epoxidation Reagents
Methylenation with Phosphorus Ylids - Wittig Reaction.
Horner-Wadsworth-Emmons Reaction
The Peterson Olefination
Elimination of OH and PhSe groups
Models for Nucleophilic Addition to α-Chiral Aldehydes.
Sulfonium Ylid Reactions
The Aldol Condensation - Stereochemistry
Chiral Enolates
The Mannich Condensation
In preparation