Total synthesis of Altersolanol B:
| Reference: | Kelly, T. R.; Montury, M. Tetrahedron Lett. 1978, 19, 4309. DOI |
| Reactions: | Allyl-OR → Allyl-H • Hydrogenolysis C-OR • Alkyl-OR → Alkyl-H • Diels-Alder, Quinone • Naphthoquinone synthesis • Alkene → Diol-1,2 • O-H → O-Alkyl (phenol) • |
| Reagents: | MeI • OsO4 • O2 • H2, Pd • Quinone • Butadiene, 1-OR • B(OAc)3 • Ag2O • |