Total Syntheses

Reaction scheme for total synthesis of the natural product Aucantene
Total synthesis of Aucantene:
Reference:Liu, H. J.; Broene, E. N. C. Can. J. Chem. 1978, 56, 306. DOI
Reactions:Diels-Alder, Yne • Cu-Vinyl+Enal • Enal+Cu-R • ConjAdd Cu-Vinyl • Wittig-methyl •
Reagents:BF3·OEt2 • Propenyl-Cu • PPh3=CH2 • Propiolaldehyde • Butadiene •