Total synthesis of Bilobanone:
| Reference: | Buchi, G.; Wuest, H. J. Org. Chem. 1969, 34, 857-860. DOI |
| Reactions: | Allylic oxidation → Enal • CompOx-Alkene/Enone+SeO2 • Mg-Alkynyl+Aldehyde • CompE+-Aldehyde/Ketone+M-R • Allyl-OR isomerization • Alkyne Oxymercuration • Furan synthesis • |
| Reagents: | SeO2 • Alkynyl-MgX • H2SO4 • HgSO4 • |