Total synthesis of Carvone (Fleming):
| Reference: | Fleming, I.; Paterson, I. Synthesis 1979, 736 |
| Reactions: | Cu-Vinyl+Enone • ConjAdd Cu-Vinyl • Mg-R → Cu-R • EnolSilane → Enone • Ketone → Enone • EnolSilane → Enone • Ketone → Enone • Ketone → EnolSilane • Ketone → EnolSilane • |
| Reagents: | LiNiPr2 • SiMe3-Cl • Propenyl-MgX • CuCl • SiMe3-Cl • DMF (solvent) • DDQ • Collidine • DDQ • Collidine • |