Total synthesis of Chrysanthemic Acid:
| Reference: | Babler, J. H.; Tortorello, A. J. J. Org. Chem. 1976, 41, 885. DOI |
| Reactions: | Wittig-isopropyl • Claisen-Johnson • CarboxEster enolate+Epoxide • Epoxide+Enolate (intram) • Cyclopropane • Epoxidation, peracid • Alkyl-OH → Aldehyde • CarboxEster → CarboxAcid • |
| Reagents: | Orthoacetate • Epoxide • LiNiPr2 • CrO3·Py2 (Collins) • PPh3=CMe2 • NaH • DMSO (solvent) • Perbenzoic acid, 3-chloro • |