Total synthesis of Desoxy-Erythrolaccin:
| Reference: | Mills, R. J.; Snieckus, V. Tetrahedron Lett. 1984, 25, 479. DOI |
| Reactions: | Alkyl-OH → Ketone • Li/H → Li-Benzyl • Li/H → Li-Aryl • Li/H → Li-Aryl • Li-Aryl+Alkyl-X • Alkyl-X+Li-R • Anthraquinone synthesis • Phenol → Quinone • Friedel-Crafts acylation • Si-Alkyl → H-Alkyl • CarboxAmide → CarboxEster • Li-Benzyl+R3SiX • Li-Aryl+Aldehyde • Lactone-5 • |
| Reagents: | BuLi(sec) • MeI • Zn° • Acetic anhydride, trifluoro • CrO3 • BuLi(n) • SiMe3-Cl • BuLi(n) • SiMe3-Cl • BuLi(n) • Benzyl-Li • Fluoride, cesium • TsOH • Aryl-Li • TMEDA • |