Total synthesis of Erythrolaccin:
| Reference: | Mills, R. J.; Snieckus, V. Tetrahedron Let. 1984, 25, 483. DOI |
| Reactions: | Li/H → Li-Aryl • Lactone-5 • Si-Aryl → Br-Aryl • Si-Aryl+Aldehyde • Aldehyde+Si-R • Li/Br → Li-Aryl • Li-Aryl+Alkyl-X • Alkyl-X+Li-R • Anthraquinone synthesis • Phenol → Quinone • Li-Aryl+Aldehyde • Friedel-Crafts acylation • Cyclohexanone • Li/H → Li-Aryl • |
| Reagents: | BuLi(sec) • SiMe3-Cl • BuLi(n) • MeI • Br2 • Aryl-Li • BuLi(n) • Zn° • Acetic anhydride, trifluoro • CrO3 • Fluoride, cesium • Aryl-Li • Aryl-Li • TMEDA • |