Total synthesis of Glabrescol:
| Reference: | Xiong, Z.; Corey, E.J. J. Am. Chem. Soc., 2000, 122, 9328-9329 DOI |
| Reactions: | Ba-Allyl+Alkyl-X • Epoxidation, dioxirane • Epoxide → Tetrahydrofuran • Ether-5 • Ether-5 • Ketal → Diol-1,2 • O-H → O-SO2Me • O-H → O-Alkyl • |
| Reagents: | Ba° (Rieke) • Acetic acid • Oxone • Sulfonic acid, Camphor • Sulfonyl chloride, methane, Py • DMAP • Acetate, sodium • Acetic acid • Carbonate, potassium • |