Total Syntheses

Reaction scheme for total synthesis of the natural product Karahanaenol
Total synthesis of Karahanaenol:
Reference:Wang, D.; Chan, T. H. Chem. Commun. 1984, 1273. DOI
Reactions:Epoxidation, peracid • CompOx-Alkene/Alkene+Peracid • Si-Allyl+Epoxide • Cationic cyclization • Cycloheptane • Silylene •
Reagents:Photochemistry • Me-Li • BF3·OEt2 • Perbenzoic acid, 3-chloro •