Total synthesis of Miltirone:
| Reference: | Lee, J.; Mei, H. S.; Snyder, J. K J. Org. Chem. 1990, 55, 5013 (see also J. Org. Chem. 1985, 50, 4996). DOI |
| Reactions: | Diels-Alder, Quinone • Bicyclo(440) • Mg-Vinyl+Ketone • Allyl-OH → Diene • Quinone synthesis • Naphthoquinone synthesis • |
| Reagents: | Vinyl-MgX • Bisulfate, potassium • Ag2O • Ultrasound • Ag2O • |