Total synthesis of Penifulvin-A:
| Reference: | Gaich, T.; Mulzer, J. J. J. Am. Chem. Soc. 2009, 131, 452–453. DOI |
| Reactions: | CarboxAcid enolate+Alkyl-X • Alkyl-X+Enolate • Ozonolysis • Lactol → Lactone • Photochemistry • Cyclopropane hydrogenolysis • Cyclopropane • Bicyclo(310) • Bicyclo(330) • |
| Reagents: | LiNiPr2 • O3 • S=C(NH2)2 • CrO3Cl·PyH (PCC) • Photochemistry • |