Total synthesis of Pentenomycin I (Carretero):
| Reference: | Rodriguez Rivero, M.; de la Rosa, J. C.; Carretero, J. C. J. Am. Chem. Soc. 2003, 125, 14992-14993. DOI |
| Reactions: | O-SiiPr3 → O-H • Sulfoxide-Ei → Enone • Ketone → Enone • Pauson-Khand • Cyclopentenone • Alkene → Diol-1,2 • |
| Reagents: | OsO4 • EneSulfoxide • NMO • |