Total Syntheses

Reaction scheme for total synthesis of the natural product Preussin
Total synthesis of Preussin:
Reference:Bach, T.; Brummerhop, H. Angew. Chem. Int. Ed. 1998, 37, 3400. DOI
Reactions:Paterno-Buchi • Photochemistry 2+2 • Hydrogenolysis C-OR • Alkyl-OR → Alkyl-H • N-C(O)OR → N-CH3 • Ether-4 • Bicyclo(320)-aza • Bicyclo(320)-oxa •
Reagents:Acetonitrile (solvent) • H2, Pd • AlH4-Li+