Total synthesis of Semperviridine:
| Reference: | Gribble, G. W.; Barden, T. C.; Johnson, D. A. Tetrahedron Lett. 1988, 44, 3195. DOI |
| Reactions: | Li/H → Li-Indole • Li/H → Li-Indole • Li-Aryl+Aldehyde • Li-Aryl+Aldehyde • Ketone → Ketone-1,2-di • Triazene synthesis • Dehydration → EnAmine • Carbazole synthesis • Diels-Alder-inverse, EnAmine • Pyridine synthesis • Retro-Diels-Alder → Arene • Allyl-OH → Enone • Sulfide → Sulfone • Aryl-S(O)nR → Aryl-H • N-H → N-SO2R • |
| Reagents: | LiNiPr2 • Acetaldehyde • MnO2 • SeO2 • Na(Hg) • Sulfonyl chloride, benzene • BuLi(n) • Bromoacetaldehyde • Hydroxide, sodium • Pyrrolyl-Li • Pyrrolyl-Li • Perbenzoic acid, 3-chloro • |