Total Syntheses

Reaction scheme for total synthesis of the natural product Turmerone, Ar- (Paterson)
Total synthesis of Turmerone, Ar- (Paterson):
Reference:Paterson, I. Tetrahedron Lett., 1979, 1519. DOI
Reactions:EnolSilane+Carbonium • Alkyl-X+Si-R • Enone → EnolSilane •
Reagents:LiNiPr2 • SiMe3-Cl • ZnBr2 • Benzyl-X •