Hans J. Reich Publications/Career

B. Sc. University of Alberta (Karl Kopecky)
Ph.D. 1968, with Donald J. Cram (UCLA). Thesis: Thermal Ring Opening and Electrophilic Substitution of [2.2]Paracyclophanes
Post. Doc. (1968-1969) with J. D. Roberts (Cal Tech)
Post. Doc. (1969-1970) with R. B. Woodward (Harvard)
University of Wisconsin (1970-2020)

Papers

  1. "Reactivities in Photosensitized Olefin Oxidations", K. R. Kopecky and H. J. Reich, Can. J. Chem. 1965, 43, 2265.
  2. "Racemization, Ring Opening, and Ring Expansion of the [2.2]Paracyclophane Nucleus Through a Diradical Intermediate", H. J. Reich and D. J. Cram, J. Am. Chem. Soc. 1967, 89, 3078.
  3. "Transannular Directive Influences in Electrophilic Substitution of [2.2]Paracyclophane", H. J. Reich and D. J. Cram, J. Am. Chem. Soc. 1968, 90, 1365.
  4. "Macro Rings. XXXV. Transannular Directive Influences in Electrophilic Substitution of Monosubstituted [2.2]Paracyclophanes", H. J. Reich and D. J. Cram, J. Am. Chem. Soc. 1969, 91, 3505.
  5. "Macro Rings. XXXVI. Ring Expansion, Racemization, and Isomer Interconversion in the [2.2]Paracyclophane System through a Diradical Intermediate", H. J. Reich and D. J. Cram, J. Am. Chem. Soc. 1969, 91, 3517.
  6. "Macro Rings. XXXVII. Multiple Electrophilic Substitution Reactions of [2.2]Paracyclophanes and Interconversions of Polysubstituted Derivatives", H. J. Reich and D. J. Cram, J. Am. Chem. Soc. 1969, 91, 3527.
  7. "Macro Rings. XXXVIII. Determination of Positions of Substituents in the [2.2]Paracyclophane Nucleus through Nuclear Magnetic Resonance Spectra", H. J. Reich and D. J. Cram, J. Am. Chem. Soc. 1969, 91, 3534.
  8. "Rigid Cyclophanes that Illustrate Stereochemical Principles", D. J. Cram, R. B. Hornby, E. A. Truesdale, H. J. Reich, M. H. Delton and J. M. Cram, Tetrahedron 1974, 30, 1757.
  9. "Nuclear Magnetic Resonance Spectroscopy. Effects of Molecular Asymmetry on Carbon-13 Chemical Shifts", J. I. Kroschwitz, M. Winokur, H. J. Reich and J. D. Roberts, J. Am. Chem. Soc. 1969, 91, 5927.
  10. "Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Spectra of Steroids", H. J. Reich, M. Jautelat, M. T. Messe, F. J. Weigert and J. D. Roberts, J. Am. Chem. Soc. 1969, 91, 7445.
  11. "Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Chemical Shifts in Acyclic and Alicyclic Alcohols", J. D. Roberts, F. J. Weigert, J. I. Kroschwitz and H. J. Reich, J. Am. Chem. Soc. 1970, 92, 1338.
  12. "Nuclear Magnetic Resonance Spectroscopy. Kinetics of a 7,7-Dicyanonorcaradiene Valence Tautomerism", H. J. Reich, E. Ciganek and J. D. Roberts, J. Am. Chem. Soc. 1970, 92, 5166.
  13. "Nuclear Magnetic Resonance Spectroscopy. Carbon-13 Chemical Shifts of Methylcyclopentanes, Cyclopentanols and Cyclopentyl Acetates", M. Christl, H. J. Reich, and J. D. Roberts, J. Am. Chem. Soc. 1971, 93, 3463.
  14. "Transannular Photochemical Ring Closure in 1,2,5,6-Tetramethylenecyclooctane. A Novel Synthesis of [3.2.2]Propellane," W. T. Borden, I. L. Reich, L. A. Sharpe, and H. J. Reich, J. Am. Chem. Soc. 1970, 92, 3808.
  15. "Transannular Photochemical Ring Closure of 1,2,5,6-Tetramethylenecyclooctane as a Synthetic Route to Small-Ring Propellanes," W. T. Borden, I. L. Reich, L. A. Sharpe, R. B. Weinberg, and H. J. Reich, J. Org. Chem. 1975, 40, 2438.
  16. "Organoselenium Stereochemistry. Configurational Stability of Dialkoxydiaryl-selenium Compounds," H. J. Reich, J. Am. Chem. Soc. 1973, 95, 964.
  17. "Synthesis of Thiabicyclo[2.2.2]octenes. Carbon-13 NMR Spectra of Bicyclic Sulfides," H. J. Reich and J. E. Trend, J. Org. Chem. 1973, 38, 2637.
  18. "Stereochemical Studies of Degenerate Silyl Rearrangements. Stereospecificity of the Tropolone and Acetylacetone Trialkylsilyl Ether Rearrangements," H. J. Reich and D. A. Murcia, J. Am. Chem. Soc. 1973, 95, 3418.
  19. "Structure and Stereolability of Triaryliodine (III) Compounds. Degenerate Isomerization of 5-Phenyl-5,H-dibenziodole," H. J. Reich and C. S. Cooperman, J. Am. Chem. Soc. 1973, 95, 5077.
  20. "Organoselenium Chemistry. α-Phenylseleno Carbonyl Compounds as Precursors for α,β-Unsaturated Ketones and Esters," H. J. Reich, I. L. Reich and J. M. Renga, J. Am. Chem. Soc. 1973, 95, 5813.
  21. "Organoselenium Chemistry. Benzeneselenenyl Trifluoroacetate Additions to Olefins and Acetylenes," Hans J. Reich, J. Org. Chem. 1974, 39, 428.
  22. "Enolate Alkylation with Bromomethyl Sulphides: Synthesis of α-Methylene Ketones and Carboxylic Acids," Hans J. Reich and James M. Renga, J. Chem. Soc., Chem. Commun. 1974, 135.
  23. "Silver Assisted Solvolysis of Halobutadienes. Evidence for a Chlorolium Ion Intermediate," I. L. Reich and H. J. Reich, J. Am. Chem. Soc. 1974, 96, 2654.
  24. "Organoselenium Chemistry. Conversion of Cyclic Ketones and β-Dicarbonyl Compounds to Enones," H. J. Reich, J. M. Renga and I. L. Reich, J. Org. Chem. 1974, 39, 2133.
  25. "A Test for Cyclic Conjugation Involving the Cyclopropyl Carbinyl Cation," H. J. Reich and J. M. Renga, Tetrahedron Lett. 1974, 2747.
  26. "Organoselenium Chemistry. Synthetic Transformations Based on Allyl Selenide Anions," H. J. Reich, J. Org. Chem. 1975, 40, 2570.
  27. "Organoselenium Chemistry. α-Lithio Selenoxides and Selenides: Preparation and Further Transformation to Olefins, Dienes and Allylic Alcohols," H. J. Reich and S. K. Shah, J. Am. Chem. Soc. 1975, 97, 3250.
  28. "Preparation of (E)(E)- and (Z)(Z)-1,4-Dibromo-1,4-Diphenylbutadienes and Conversion to Mono and Dilithio Derivatives," H. J. Reich and I. L. Reich, J. Org. Chem. 1975, 40, 2248.
  29. "Organoselenium Chemistry. Addition of Tolueneselenenyl Chloride to Ethylene: Concerning the Reported Isolation of a Stable Episelenurane," J. H. Reich and J. E. Trend, Can. J. Chem. 1975, 53, 1922.
  30. "Organoselenium Chemistry. Conversion of Ketones to Enones by Selenoxide syn-Elimination," H. J. Reich, J. M. Renga and I. L. Reich, J. Am. Chem. Soc. 1975, 97, 5434.
  31. "SeIenium Stabilized Anions. Conversion of β-Hydroxy Selenides to Olefins," H. J. Reich and F. Chow, J. Chem. Soc., Chem. Commun. 1975, 790.
  32. "Organoselenium Chemistry. Preparation and Reactions of Benzeneselenenamides," H. J. Reich and J. M. Renga, J. Org. Chem. 1975, 40, 3313.
  33. "Stereochemical Dependence of Geminal Selenium-Carbon Coupling Constants," H. J. Reich and J. E. Trend, J. Chem. Soc., Chem. Commun. 1976, 310.
  34. "Organoselenium Chemistry. Mechanism and Stereochemistry of N,N-Dimethylbenzene-selenenamide Addition to Dimethyl Acetylenedicarboxylate. Configurationally Labile Olefins," H. J. Reich, J. M. Renga and J. E. Trend, Tetrahedron Lett. 1976, 2217.
  35. "Organoselenium Chemistry. Intra- and Intermolecular Trapping of Selenenic Acids Formed by Selenoxide Elimination. Formation of A Selenium Ylide," H. J. Reich and J. E. Trend, J. Org. Chem. 1976, 41, 2503.
  36. "Selenium Stabilized Anions. Synthetic Transformations Based on Propargyl Selenoxides," H. J. Reich and S. K. Shah, J. Am. Chem. Soc. 1977, 99, 263.
  37. "Selenium Stabilized Anions. Selenoxide syn-Elimination and Sila-Pummerer Rearrangement of α-Silyl Selenoxides," H. J. Reich and S. K. Shah, J. Org. Chem. 1977, 42, 1773.
  38. "Seleninic Acids as Catalysts for Oxidations of Olefins and Sulfides Using Hydrogen Peroxide," H. J. Reich, F. Chow and S. L. Peake, Synthesis, 1978, 299.
  39. "Syn Elimination of Alkyl Selenoxides. Side Reactions Involving Selenenic Acids, Structural and Solvent Effects on Rates," H. J. Reich, S. Wollowitz, J. E. Trend, F. Chow and D. F. Wendelborn, J. Org. Chem. 1978, 43, 1697.
  40. "Synthesis of Chlorolium Ion Precursors; Solvolysis of Halobutadienes," I. L. Reich, C. L. Haile and H. J. Reich, J. Org. Chem. 1978, 43, 2402.
  41. "Hypervalent Organoiodine Chemistry. Syn Elimination of Alkyl Iodoso Compounds," H. J. Reich and S. L. Peake, J. Am. Chem. Soc. 1978, 100, 4888.
  42. "Conversion of Allyl Alcohols to Dienes by Sulfoxide and Selenoxide syn Elimination. Synthesis of PCB Arene Oxides," H. J. Reich, I. L. Reich and S. Wollowitz, J. Am. Chem. Soc. 1978, 100, 5981.
  43. "Diphenyl Diselenide and Benzeneselenenyl Chloride," H. J. Reich, M. L. Cohen, and P. D. Clark, Org. Synth. 1979, 59, 141.
  44. "Selenium Stabilized Carbanions. Ylide Formation During Alkylation of Selenium and Sulfur Substituted Enolates," H. J. Reich and M. L. Cohen, J. Am. Chem. Soc. 1979, 101, 1307.
  45. "Silyl Ketone Chemistry. A New Regiospecific Route to Silyl Enol Ethers," H. J. Reich, J. J. Rusek and R. E. Olson, J. Am. Chem. Soc. 1979, 101, 2225.
  46. "Organoselenium Chemistry. Dealkylation of Amines with Benzeneselenol," H. J. Reich and M. L. Cohen, J. Org. Chem. 1979, 44, 3148.
  47. "Selenium Stabilized Carbanions. Preparation of α-Lithio Selenides and Application to the Synthesis of Olefins by Reductive Elimination of β-Hydroxy Selenides and Selenoxide Syn Elimination," H. J. Reich, F. Chow and S. K. Shah, J. Am. Chem. Soc. 1979, 101, 6638.
  48. "Selenium Stabilized Carbanions. α-Lithio Selenoxides as Reagents for the Synthesis of Olefins, Allyl Alcohols and Dienes," H. J. Reich, S. K. Shah and F. Chow, J. Am. Chem. Soc. 1979, 101, 6648.
  49. "Synthetic Applications of Organoselenium Reagents. Synthesis of Epi-7-Hydroxymyoporone," H. J. Reich, P. M. Gold and F. Chow, Tetrahedron Lett. 1979, 4433.
  50. "Preparation of β-Dicarbonyl Enones: 2-Acetyl-2-cyclohexene-1-one," J. M. Renga and H. J. Reich, Org. Synth. 1979, 59, 58.
  51. "Silyl Ketone Chemistry. Preparation of Siloxy Allenyl- and Allyllithium Reagents," H. J. Reich, R. E. Olson and M. C. Clark, J. Am. Chem. Soc. 1980, 102, 1423.
  52. "Organoselenium Chemistry. Formation of Acetylenes and Allenes by syn-Elimination of Vinyl Selenoxides," H. J. Reich and W. W. Willis, Jr., J. Am. Chem. Soc. 1980, 102, 5967.
  53. "Selenium Stabilized Carbanions. Acidity of Allyl and Vinyl Sulfides and Selenides," H. J. Reich and W. W. Willis, Jr., J. Org. Chem. 1980, 45, 5227.
  54. "Selenium Stabilized Anions. Preparation of α,β-Unsaturated Carbonyl Compounds Using Propargyl Selenides. Synthesis of (+)-7-Hydroxymyoporone," H. J. Reich, S. K. Shah, P. M. Gold and R. E. Olson, J. Am. Chem. Soc. 1981, 103, 3112.
  55. "Vinyl Selenides and Selenoxides: Preparation, Conversion to Lithium Reagents, Diels-Alder Reactivity, and Some Comparisons with Sulfur Analogs," H. J. Reich, W. W. Willis, Jr., and P. D. Clark, J. Org. Chem. 1981, 46, 2775.
  56. "Synthesis of Chlorinated and Brominated Biphenyl Oxides", I. L. Reich and H. J. Reich, J. Org. Chem. 1981, 46, 3721.
  57. "The Selenenate-Selenoxide Equilibrium. Kinetics and Thermodynamics," in "Selenium in Biology and Medicine," J. E. Spallholz, J. I. Martin, and H. E. Ganther, Eds., H. J. Reich and S. I. Wollowitz, AVI Publishing Co., Inc., Westport, CT, 1981, p. 460.
  58. "Selenium Stabilized Carbanions. Synthesis of Enals and Silyl Enones using 1,3-Bis(phenylseleno) -propene," H. J. Reich, M. C. Clark and W. W. Willis, Jr., J. Org. Chem. 1982, 47, 1618.
  59. "Silyl Ketone Chemistry. Synthesis and Reactions of Olefinic and Acetylenic Silyl Ketones," H. J. Reich and M. J. Kelly, J. Am. Chem. Soc. 1982, 104, 1119.
  60. "Organoselenium Chemistry. Characterization of Reactive Intermediates in the Selenoxide Syn Elimination: Selenenic Acids and Selenolseleninate Esters," H. J. Reich, C. A. Hoeger and W. W. Willis, Jr., J. Am. Chem. Soc. 1982, 104, 2936.
  61. "Stable Selenenic Acids", H. J. Reich, W. W. Willis, Jr., and S. Wollowitz, Tetrahedron Lett. 1982, 23, 3319.
  62. "Conversion of Allyl Alcohols to l,3-Dienes by Sequential Sulfenate-Sulfoxide [2,3] Sigmatropic Rearrangement and Syn Elimination," H. J. Reich and S. Wollowitz, J. Am. Chem. Soc. 1982, 104, 7051.
  63. "Silyl Ketone Chemistry. Preparation and Reactions of Unsaturated Silyl Ketones," H. J. Reich, M. J. Kelly, R. E. Olson and R. C. Holtan, Tetrahedron 1983, 39, 949.
  64. "Kinetics, Thermodynamics, and Stereochemistry of the Allyl Sulfoxide-Sulfenate and Selenoxide-Selenenate [2,3] Sigmatropic Rearrangements," H. J. Reich, K. E. Yelm and S. Wollowitz, J. Am. Chem. Soc. 1983, 105, 2503.
  65. "Carbon-Carbon Bond Formation and Functional Group Interconversion Using Organoselenium Reagents," H. J. Reich, Proceedings of the Fourth International Conference on the Organic Chemistry of Selenium and Tellurium, F. J. Berry and W. R. McWhinnie, Eds., The University of Aston in Birmingham, 1983, p. 258.
  66. "Organoselenium Chemistry. Preparation of Allyl and Homoallyl Amines by Aminomethylation of Phenylseleno-Substituted Allyl Tin Reagents," H. J. Reich, M. C. Schroeder and I. L. Reich, Isr. J. Chem., 1984, 24, 157.
  67. "Organotin Chemistry. Preparation of 2,3-Disubstituted 1,3-Butadienes Using 3-Bistrimethylstannyl-1,3-Butadiene and 1,4-Bistrimethylstannyl-2-butyne," H. J. Reich, K. E. Yelm, and I. L. Reich, J. Org. Chem. 1984, 49, 3438.
  68. "Silyl Ketone Chemistry. Preparation of Eremophilane and Eudesmane Sesquiterpenes by Vinylallene Cycloaddition," H. J. Reich and E. E. Eisenhart, J. Org. Chem. 1984, 49, 5282.
  69. "Lithium Metalloid Exchange Reactions. Kinetic Evidence for An Intermediate in the Lithium-Iodine Exchange," H. J. Reich, N. H. Phillips, and I. L. Reich, J. Am. Chem. Soc. 1985, 107, 4101.
  70. "Organoselenium Chemistry. A Study of Intermediates in the Fragmentation of Aliphatic Ketoselenoxides. Characterization of Selenoxides, Selenenamides and Selenolseleninates by 1H, 13C and 77Se NMR," H. J. Reich, C. A. Hoeger and W. W. Willis, Jr., Tetrahedron 1985, 41, 4771.
  71. "Lithium-Metalloid Exchange Reactions. Observation of Lithium Pentaalkyl/aryl Tin Ate Complexes," H. J. Reich and N. H. Phillips, J. Am. Chem. Soc. 1986, 108, 2102. (Communication)
  72. "Organoselenium Chemistry. Alkylation of Acid, Ester, Amide and Ketone Enolates with Bromomethyl Benzyl Selenide and Sulfide: Preparation of Selenocysteine Derivatives," H. J. Reich, C. P. Jasperse, and J. M. Renga, J. Org. Chem. 1986, 51, 2981. (Article)
  73. "Silyl Ketone Chemistry. Preparation and Reactions of Silyl Allenol Ethers. Diels-Alder Reaction of Siloxy Vinylallenes Leading to Sesquiterpenes," H. J. Reich, E. K. Eisenhart, R. E. Olson, and M. J. Kelly, J. Am. Chem. Soc. 1986, 108, 7791.
  74. "Silyl Ketone Chemistry. Synthesis of Regio- and Stereochemically Pure Enol Silyl Ethers Using α-Phenylthio Silyl Ketones," H. J. Reich, R. C. Holtan and S. I. Borkowsky, J. Org. Chem. 1987, 52, 312.
  75. "Preparation of 3-Substituted-4-methyl Furans: 3-Iodo-4-methyl- and 3-Formyl-4-methyl Furan," H. J. Reich and R. E. Olson, J. Org. Chem. 1987, 52, 2315.
  76. "Organoselenium Chemistry. Redox Chemistry of Selenocysteine Model Systems," H. J. Reich and C. P. Jasperse, J. Am. Chem. Soc. 1987, 109, 5549. (Communication)
  77. "Synthesis of 14C-Labeled Perfluorooctanoic and Perfluorodecanoic Acids; Purification of Perfluorodecanoic Acid," I. L. Reich, H. J. Reich, L. A. Manahan, R. E. Peterson, J. Labelled Compounds, 1987, 1235. (Article)
  78. "Lithium Pentaalkyl/Aryl Tin Ate Complexes as Intermediates in the Lithium-Tin Exchange Reaction," H. J. Reich and N. H. Phillips, Pure Applied Chem., 1987, 59, 1021-1026.
  79. "Poly[1-trimethylsilyl)2-propen-1-one]: The First Example of a Poly (α,β-Unsaturated Acylsilane)," A. S. Gozdz, H. J. Reich and M. D. Bowe, Macromolecules, 1987, 20, 2031. (Article)
  80. "Organoselenium Chemistry. Preparation of Allylic, Allenic and Propargylic Stannanes by Substitution of Phenylseleno with Trimethylstannyl," H. J. Reich and J. W. Ringer, J. Org. Chem. 1988, 53, 455. (Communication)
  81. "Organoselenium Chemistry: Preparation and Reactions of 2,4,6-Tri-t-butylbenzeneselenenic Acid," H. J. Reich and C. P. Jasperse, J. Org. Chem. 1988, 53, 2389. (Communication)
  82. "Stereochemistry of Vinylallene Cycloadditions," H. J. Reich, E. K. Eisenhart, W. L. Whipple and M. J. Kelly, J. Am. Chem. Soc. 1988, 110, 6432. (Article)
  83. "The Lithium-Metalloid Exchange Reaction. NMR Studies of the Phenyllithium-Iodobenzene Exchange," H. J. Reich and D. P. Green, J. Am. Chem. Soc. 1989, 111, 3444. (Communication)
  84. "Spectroscopic and Reactivity Studies of Lithium Reagent - HMPA Complexes," H. J. Reich and D. P. Green, J. Am. Chem. Soc. 1989, 111, 8729. (Communication)
  85. "Acylsilane Chemistry. Synthesis of Regio and Stereoisomerically Defined Enol Silyl Ethers Using Silyl Ketones," H. J. Reich, R. C. Holtan and C. Bolm, J. Am. Chem. Soc. 1990, 112, 5609. (Article)
  86. "Preparation of the 5,6-Arene Oxide of 3,3',4,4'-Tetrachlorobiphenyl. Decarboxylative Elimination as an Effective Last Step," I. L. Reich and H. J. Reich, J. Org. Chem. 1990, 55, 2282. (Communication)
  87. "Synthesis and Lithographic Evaluation of a Poly(acylsilane)," A. S. Gozdz, H. J. Reich, M. D. Bowe, in "Silicon-Based Polymer Science", J. M. Zeigler and F. W. G. Fearon, Eds., 1990, p. 693. (Article)
  88. "The Lithium-Selenium Exchange. Stereochemistry of alpha-Lithio Selenides and Sulfides," H. J. Reich and M. D. Bowe, J. Am. Chem. Soc. 1990, 112, 8994. (Communication)
  89. "The Lithium-Metalloid Exchange. Dynamics and Equilibrium in the Li/I and Li/Te Exchange in Tetrahydrofuran: Iodine Tellurium and Mercury Ate Complexes," H. J. Reich, D. P. Green and N. H. Phillips, J. Am. Chem. Soc. 1991, 113, 1414. (Communication)
  90. "The Use of N,N'-Dimethoxy-N,N'-dimethylurea as a Carbonyl Dication Equivalent in Organometallic Addition Reactions. Synthesis of Unsymmetrical Ketones," W. L. Whipple and H. J. Reich, J. Org. Chem. 1991, 56, 2911. (Note)
  91. "Direct Nuclear Magentic Resonance Spectroscopic Determination of Organolithium Ion Pair Structures in THF/HMPA Solution," H. J. Reich and J. P. Borst, J. Am. Chem. Soc. 1991, 113, 1835. (Communication)
  92. "Asymmetric Induction in the Oxidation of [2.2]Paracyclophane-Substituted Selenides. Application of Chirality Transfer in the Selenoxide [2,3] Sigmatropic Rearrangement," H. J. Reich and K. E. Yelm, J. Org. Chem. 1991, 56, 5672-5679. (Article)
  93. "In Vitro Metabolism of [14C]4-Chlorobiphenyl and [14C]2,2',5,5'-Tetrachlorobiphenyl by Hepatic Microsomes from Rats and Pigeons. Evidence Against an Obligatory Arene Oxide in Aromatic Hydroxylation Reactions," J. T. Borlakoglu, K. D. Haegele, H. J. Reich, R. R. Dils and J. P. G. Wilkins. Int. J. Biochem. 1991, 23, 1427. (Article)
  94. "Mechanism of the Lithium-Tellurium, Lithium Iodine and Lithium-Mercury Exchange Reactions: Hypervalent Tellurium and Iodine Ate Complexes," H. J. Reich, D. P. Green, N. H. Phillips and J. P. Borst, Phosphorus, Sulfur, Silicon, 1992, 67, 83. (Article)
  95. "The Lithium-Tin Exchange Reaction. Stereochemistry at Tin," H. J. Reich, J. P. Borst, M. B. Coplien and N. H. Phillips. J. Am. Chem. Soc. 1992, 114, 6577. (Communication).
  96. "The First Organoselenium Ate Complex," Hans J. Reich, Birgir Ö. Gudmundsson and Robert R. Dykstra, J. Am. Chem. Soc. 1992, 114, 7937. (Communication).
  97. "Stereochemistry of a Cyclohexyllithium Reagent. A Case of Higher Configurational Stability in Strongly Coordinating Media", Hans J. Reich, Marco A. Medina, Michael D. Bowe, J. Am. Chem. Soc. 1992, 114, 11003. (Communication)
  98. "Synthesis of 2,3-Disubstituted 1,2-Butadienes from Organotin Precursors and Butadienyl Lithium Reagents. Diels-Alder Reactivity," H. J. Reich, I. L. Reich, K. E. Yelm, J. E. Holladay, and D. Gschneidner", J. Am. Chem. Soc. 1993, 115, 6625-35. (Article).
  99. "Structure Effects of Ion Pair Separation: Planar and Pyramidal Sulfur and Silicon Substituted Carbanions," H. J. Reich, R. R. Dykstra, J. Am. Chem. Soc. 1993, 115, 7041. (Communication).
  100. "A Nuclear Magnetic Resonance Spectroscopic Technique for the Characterization of Lithium Ion Pair Structures in THF and THF/HMPA Solution," H. J. Reich, J. P. Borst, R. R. Dykstra, D. P. Green J. Am. Chem. Soc. 1993, 115, 8728-41 (Article)
  101. "Effect of Ion Pair Separation on Inversion and Rotation of Sulfur, Selenium, and Silicon Stabilized Organolithium Reagents," Hans J. Reich, Robert R. Dykstra Angew. Chem., Int. Ed. Engl. 1993, 32, 1469-70. (Communication).
  102. "Lithium-Metalloid Exchange: Reactivity Studies of an Allenyl Lithium Reagent Using an Isomeric Pair of Allenyl and Prop-2-ynyl Stannanes," Hans J. Reich and J. Derek Mason, and Jonathan E. Holladay, J. Chem. Soc., Chem. Commun. 1993, 1481-3. (Communication).
  103. "Trimethylstannyl- and Tributylstannyllithium: Solution Structure in Ether, THF and HMPA," Hans J. Reich, Joseph P. Borst, Robert R. Dykstra, Organometallics 1994, 13, 1. (Communication).
  104. "Solution Structure of Lithium Benzeneselenolate and Lithium Diphenylphosphide: NMR Identification of Cyclic Dimers and Mixed Dimers," Hans J. Reich and Robert R. Dykstra, Organometallics 1994, 13, 4578. (Article).
  105. "Solution Ion Pair Structure of 2-Lithio-1,3-Dithianes in THF and THF-HMPA", Hans J. Reich, Joseph P. Borst, Robert R. Dykstra, Tetrahedron 1994, 50, 5869. (Article).
  106. "Chelation Effects in Chiral Organolithium Reagents," Hans J. Reich and Klaus J. Kulicke, J. Am. Chem. Soc. 1995, 117, 6621-22. (Communication).
  107. "Solution Structure of Allenyl-Propargyllithium Reagents", Hans J. Reich and Johnathan E. Holladay, J. Am. Chem. Soc. 1995, 117, 8470-71. (Communication).
  108. "The Origin of Regioselectivity in an Allenyllithium Reagent," Hans J. Reich, Johnathan E. Holladay, J. Derek Mason, William H. Sikorski, J. Am. Chem. Soc. 1995, 117, 12137-12150. (Article).
  109. "Dynamics of Solvent Exchange in Organolithium Reagents. Lithium as a Center of Chirality," Hans J. Reich and Klaus J. Kulicke, J. Am. Chem. Soc. 1996, 118, 273-274. (Communication).
  110. "Tetrakis(mu-3-2-methyl-5-thienyl)tetrakis(diethylether-O-)-tetrahedro-tetralithium, [Li4(C5H5S)4-4(C4H10O)]," Douglas R. Powell, Wesley L. Whipple and Hans J. Reich, Acta Cryst. Sect. C 1996, C52, 1346-8. (Article).
  111. "Solution Structure of 2-[(Dimethylamino)-methyl]phenyllithium," Hans J. Reich and Birgir O. Gudmundsson, J. Am. Chem. Soc. 1996, 118, 6074-6075. (Communication).
  112. "Solution Structure of Silyl-Substituted Allenyl-Propargyllithium Reagents" Hans J. Reich and Johnathan E. Holladay, Angew. Chem. Int. Ed., Engl. 1996, 35, 2365-67. (Communication).
  113. "Tris(trimethylsilyl)methane as an Internal 13C NMR Chemical Shift Thermometer," William H. Sikorski, Aaron W. Sanders and Hans J. Reich, Magn. Resonan. Chem. 1998, 36, S118-S124. (Article).
  114. "Triple Ion Formation in Localized Organolithium Reagents" Hans J. Reich, William H. Sikorski, Birgir Ö. Gudmundsson and Robert R. Dykstra, J. Am. Chem. Soc. 1998, 120, 4035. (Communication).
  115. "Aggregation and Reactivity of Phenyllithium Solutions," Hans J. Reich, D. Patrick Green, Marco A. Medina, Wayne S. Goldenberg, Birgir Ö. Gudmundsson, Robert R. Dykstra, and Nancy H. Phillips, J. Am. Chem. Soc. 1998, 120, 4035. (Article).
  116. "Ergosteroids III. Seco-Steroids Related to Dehydroepiandrosterone," Ieva L. Reich, Henry Lardy, Yong Wei, Padma Marwah, Nancy Kneer, Douglas R. Powell and Hans J. Reich Steroids, 1998, 63 542. (Article).
  117. "The Regioselectivity of Addition of Organolithium Reagents to Enones: The Role of HMPA," Hans J. Reich and William H. Sikorski, J. Org. Chem. 1999, 64, 14-15. (Communication)
  118. "Solution Structure and Stereochemistry of Alkyl- and Silyl-Substituted Allenyl-Propargyllithium Reagents," Hans J. Reich, Johnathan E. Holladay, Tamara G. Walker and Jennifer L. Thompson, J. Am. Chem. Soc. 1999, 121, 9769-9780.(Article)
  119. "Solvent-Dependent Lithium-Bridging in Allenyl- Propargyllithium Reagents," Hans J. Reich and Jennifer L. Thompson Org. Letters 2000, 2, 783-786. (Communication)
  120. "Chelated Aryllithium Reagents -- Ring Size and Chelating Group Effects," Hans J. Reich, Wayne S. Goldenberg, Aaron W. Sanders and C. Christoph Tzschucke Org. Letters 2001, 3, 33-36. (Communication)
  121. "The Regioselectivity of Addition of Organolithium Reagents to Enones and Enals: The Role of HMPA," William H. Sikorski and Hans J. Reich J. Am. Chem. Soc. 2001, 123, 6527-6535.(Article)
  122. "Amine-Chelated Aryllithium Reagents - Structure and Dynamics." Hans J. Reich, Wayne S. Goldenberg, Birgir Ö. Gudmundsson, Aaron W. Sanders, Klaus J. Kulicke, Katya Simon, and Ilia A. Guzei J. Am. Chem. Soc. 2001, 123, 8087-8079.(Article)
  123. "Identification and Mechanistic Consequences of Contact and Solvent-Separated Ion Pair Structures in Organolithium Chemistry." Hans J. Reich, Aaron W. Sanders, Martin J. Bevan, Wiliam H. Sikorski, and Robert R. Dykstra Latvian J. Chem. 2002, 93-103.(Article)
  124. "Ergosteroids V: Preparation and Biological Activity of Various D-Ring Derivatives in the 7-Oxo-dehydroepiandrosterone Series," Ieva L. Reich, Hans J. Reich, Nancy Kneer and Henry Lardy, Steroids, 2002, 67, 221-233. (Article)
  125. "Are Ate Complexes True Intermediates in the Lithium-Metalloid Exchange? Subtle Effects of Ion Pair Structure in Lithium-Tellurium and Lithium-Selenium Exchange Reactions," Hans J. Reich, Martin J. Bevan, Birgir Ö. Gudmundsson and Craig L. Puckett, Angew. Chem. Int. Ed. Engl. 2002, 41, 3436-3439. (Communication)
  126. "The Effect of HMPA on the Reactivity of Epoxides, Aziridines and Alkyl Halides with Organolithium Reagents," Hans J. Reich, Aaron W. Sanders, Adam T. Fiedler, and Martin J. Bevan, J. Am. Chem. Soc. 2002, 124, 13386-13387. (Communication)
  127. "The Role of Ate Complexes in the Lithium-Sulfur, Lithium-Selenium and Lithium-Tellurium Exchange Reactions," Hans J. Reich, Birgir Ö. Gudmundsson, D. Patrick Green, Martin J. Bevan, and Ieva L. Reich, Helv. Chim. Acta 2002, 85, 3748-3772. (Article)
  128. "Amine and Ether Chelated Aryllithium Reagents - Structure and Dynamics." Hans J. Reich, Wayne S. Goldenberg, Aaron W. Sanders, Kevin L. Jantzi and C. Christoph Tzschucke, J. Am. Chem. Soc. 2003, 125, 3509 (full paper).
  129. "Pyrrolidine Chelated Aryllithium Reagents," Hans J. Reich, Wayne S. Goldenberg and Aaron W. Sanders, ARKIVOC 2004, (xiii) 97-129 (Full Paper).
  130. "Reaction of Metalated Nitriles with Enones," Hans J. Reich,* Margaret M. Biddle and Robert J. Edmonston J. Org. Chem. 2005, 70, 3375-3382. (Full Paper)
  131. "The Strength of Parallel-Displaced Arene-Arene Interactions in Chloroform," Benjamin W. Gung, Xiaowen Xue, and Hans J. Reich J. Org. Chem. 2005, 70, 3641-3644. (Full Paper)
  132. "Solution Structure and Chelation Properties of 2-Thienyllithium Reagents," Kevin L. Jantzi, Craig L. Puckett, Ilia A. Guzei and Hans J. Reich, J. Org. Chem. 2005, 70,7520-7529.
  133. "Mechanism of the Lithium-Iodine Exchange in an Iodothiophene," Hans J. Reich, and Wesley L. Whipple, Can. J. Chem. 2005, 83, 1577.
  134. "Studies on the Reactive Species in Fluoride-Mediated Carbon-Carbon Bond-Forming Reactions: Carbanion Formation by Desilylation with Fluoride and Enolates," Margaret M. Biddle and Hans J. Reich, J. Org. Chem. 2006, 71, 4031-4039. (Article) JOC Cover
  135. "Interconversion of Contact and Separated Ion Pairs in Silyl- and Arylthio-Substituted Alkyllithium Reagents," Hans J. Reich, William H. Sikorski, Jennifer L. Thompson, Aaron W. Sanders, Amanda C. Jones, Org. Lett. 2006, 8, 4003-4006. (Communication)
  136. "Solution and Solid-State Structures of Lithiated Phenyloxazolines," Kevin L. Jantzi, Ilia A. Guzei, Hans J. Reich, Organometallics. 2006, 25, 5380-5395. (Article)
  137. "Reactivity of Individual Organolithium Aggregates - a RINMR Study of n-Butyllithium and 2-Methoxy-6-(methoxymethyl)phenyllithium," Amanda C. Jones, Aaron W. Sanders, Martin J. Bevan and Hans J. Reich, J. Am. Chem. Soc. 2007, 129, 3492-3493. (Article)
  138. "Reactivity of the Triple Ion and Separated Ion Pair of Tris(trimethylsilyl)methyllithium with Aldehydes: A RINMR Study," Amanda C. Jones, Aaron W. Sanders, William H. Sikorski, Kristen L. Jansen, Hans J. Reich J. Am. Chem. Soc. 2008, 130, 6060-6061 (Communication).
  139. "Unexpected Crystallization of 1,3-Bis(4-fluorophenyl)propan-2-one in Paratone Oil," Ilia A. Guzei,* Kristopher J. Kolonko and Hans J. Reich Acta Cryst. 2007, E63, o4094.
  140. "Stabilization of Ketone and Aldehyde Enols by Formation of Hydrogen Bonds to Phosphazene Enolates and Their Aldol Products," Kristopher J. Kolonko and Hans J. Reich J. Am. Chem. Soc. 2008, 130, 9668 (Communication)
  141. "Multinuclear NMR Study of the Solution Structure and Reactivity of Tris(trimethylsilyl)methyllithium and its Iodine Ate Complex" Hans J. Reich, William H. Sikorski, Aaron W. Sanders, Amanda C. Jones, Kristin N. Plessel J. Org. Chem. 2009, 74, 719 (Article)
  142. "Solution Structures of Lithium Enolates of Cyclopentanone, Cyclohexanone, Acetophenones, and Benzyl Ketones. Triple Ions and Higher Lithiate Complexes," Kolonko, Biddle, Guzei, Reich J. Am. Chem. Soc. 2009, 131, 11525-11534. (Article)
  143. "Structure and Dynamics of α-Aryl Amide and Ketone Enolates: THF, PMDTA, TMTAN, HMPA, and Crypt-Solvated Lithium Enolates, and Comparison with Phosphazenium Analogues" Kristopher J. Kolonko, Ilia A. Guzei, and Hans J. Reich J. Org. Chem. 2010, 75, 6163-6172. (Article)
  144. "Mechanistic Studies of the Lithium Enolate of 4-Fluoroacetophenone: Rapid-Injection NMR Study of Enolate Formation, Dynamics, and Aldol Reactivity" Kristopher J. Kolonko, Daniel J. Wherritt, and Hans J. Reich J. Am. Chem. Soc. 2011, 133, 16774-16777. (Communication)
  145. "A Rapid Injection NMR Study of the Reaction of Organolithium Reagents with Esters, Amides, and Ketones." Kristin N, Plessel, Amanda C. Jones, Daniel J. Wherritt, Rebecca M. Maksymowicz, EricT. Poweleit, and Hans J. Reich Org. Lett., 2015, 17, 2310-2313. (Communication) ACS Editor's Choice
  146. "Chiral hemicucurbit[8]uril as an anion receptor: selectivity to size, shape and charge distribution" Sandra Kaabel, Jasper Adamson, Filip Topic, Anniina Kiesil, Elina Mario Oeren, Mart Reimund, Elena Prigorchenko, Aivar Lookene, Hans J. Reich, Kari Rissanen and Riina Aav RSC Chem.Sciene 2016 Reviews
  147. "Organoselenium Oxidations," H. J. Reich, in "Oxidation in Organic Chemistry Part C", W. W. Trahanovsky, Ed., Academic Press, New York, 1978, p. 1. (Review)
  148. "Functional Group Manipulation Using Organoselenium Reagents," H. J. Reich, Acc. Chem. Res. 1979, 12, 22. (Review)
  149. "Carbon-Carbon Bond Formation and Functional Group Interconversion Using Organoselenium Reagents," H. J. Reich, Proceedings of the Fourth International Conference on the Organic Chemistry of Selenium and Tellurium, F. J. Berry and W. R. McWhinnie, Eds., The University of Aston in Birmingham, 1983, p. 258.
  150. "Selenium Stabilized Carbanions", H. J. Reich in "Modern Organoselenium Chemistry," D. Liotta, Ed., Wiley, New York, p. 243, 1987. (Review)
  151. "[2,3] Sigmatropic Rearrangements of Organoselenium Compounds," H. J. Reich in "Modern Organoselenium Chemistry," D. Liotta, Ed., Wiley, New York, p. 365, 1987. (Review)
  152. "Preparation of α, β-Unsaturated Carbonyl Compounds and Nitriles by Selenoxide Elimination," Hans J. Reich, Susan Wollowitz, Organic Reactions 1993, 44, 1-296. (Review)
  153. Hans J. Reich, Section Editor of "Encyclopedia Of Reagents for Organic Synthesis," Wiley, Chichester, L. A. Paquette, Editor, 1995.
  154. "Introducing JCE ChemInfo: Organic," Hans J. Reich, J. Chem. Edu. 2005, 82, 495. (Column Editor).
  155. "What's Going on with These Lithium Reagents?" Hans J. Reich J. Org. Chem. 2012, 77, 5471-5491. (Perspective) JOC Cover
  156. "Role of Organolithium Aggregates and Mixed Aggregates in Organolithium Mechanisms." Hans J. Reich Chem. Rev. 2013, 113, 7130-7178. (Review)
  157. "Why Nature Chose Selenium" Hans J. Reich and Robert J. Hondal ACS Chem. Biol. 2016, 11, 821-841. (Review)

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